N,N,N′,N′-Tetramethylethane-1,2-diamine (TMEDA)
نویسندگان
چکیده
منابع مشابه
[(TM EDA)2Li4Cl4(H20)2]*2 TMEDA: stabförmige vierkernige Li-Komplexe verknüpft durch TMEDA [(TM EDA)2Li4Cl4(H20)2]-2 TMEDA: Stick-Like Tetranuclear Li Complexes Connected by TMEDA
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
متن کاملA Cu(II) mediated new desulfurization pathway involving elimination of ethylene sulfide.
Reaction of thiodiacetate anion (tda) with [Cu(TMEDA)(NO3)2] (TMEDA = N,N,N'N'-tetramethyl ethylene-diamine) in a stoichiometric ratio afforded the complex {[Cu(TMEDA)(tda)]·(H2TMEDA)(NO3)2·H2O} (1). When [Cu(TMEDA)(NO3)2] was added in excess, it yielded a μ-oxalato complex {[Cu2(TMEDA)2(μ-ox)(H2O)2](NO3)2·2CH3CN} (2). The reaction involves a facile room temperature desulfurization of the thiod...
متن کاملPREPARATION AND MOLECULAR STRUCTURE OF TRlS[(N, N, N\' , N\' - DIAMINE) L1TI-IIUMj TETRAMETHYLETHYLENE HEXAMETHYLSAMARATE(III), {[Li(TMEDA)b [Sm(CH3)6]}.THF
Inc Sm(1)(TIIFh reacts with mcthylllthlUm In TIIF In the prese nce of lclram c lhyt c lhy lcn c d lamln e, TMEDA , 10 gIve 1[1 .J(l ·MI :I)A)h[Sm«('I I)61}. J'IIF. Tl1c complex has been ch;lractcnzcd hy elemenl al analyses, lit spectrum and magnetic mcasurem ent . Molecular .lOd clymsl .SruClUrc of thl! complcx hoo been determmed by a sIngle cryst .. ! X - ray diffractIOn . The crystalS ar...
متن کاملChalcogenospecific ZnSs ( TMEDA ) Synthesis of 1 , 2 - Se &
The compound (C5H5)2TiS5 has allowed the rational syntheses of many sulfur homoand heterocycles.' This reagent serves as a reliable source of the S52unit, thereby defining a route to cyclic compounds of the type cyclo-S5+, and related Se-S rings.2 The coproducts and starting reagents are fairly chemically inert thus minimizing nucleophile-induced rearrangements of unstable cyclic polysulfanes. ...
متن کامل3-Methylbenzene-1,2-diamine
The title compound, C7H10N2, was synthesized from 2-methyl-6-nitro-aniline by a reduction reaction. In the crystal, molecules are linked via N-H⋯N hydrogen bonds, forming two-dimensional networks lying parallel to (100). These networks are stabilized by C-H⋯π and N-H⋯π inter-actions.
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ژورنال
عنوان ژورنال: Synlett
سال: 2013
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-0033-1339856